in this paper, a modified sol-gel method using peroxotitanic acid sol (pta) was applied for the preparation of tio2 nanostructured thin films on glass plates. the peroxotitanic acid sol was synthesized using titanium isopropoxide, isopropylalchol, h2o and hydrogen peroxide. tio2 films were then calcined at 500oc and characterized by x-ray diffraction (xrd) and scanning electron microscopy (sem)...

Ridge and buried channel waveguides were fabricated on different substrates such as SiO2-on-Si, Si, glass wafers and Printed Circuit Boards by a sol-gel processing together with a photolithography process using photopatternable hybrid sol-gel materials. Thick sol-gel films of up to 100 microns were developed using a modified sol-gel process and ridge waveguides with vertical smooth sidewalls we...

This study describes a new means to conduct molecular recognition-based analysis using mass spectrometry. Taking advantage of the unique characteristic of the absorption capacity of the TiO(2) sol-gel material in the UV region, a TiO(2) sol-gel-deposited thin film was employed as the sample substrate to assist in UV laser desorption/ionization of analytes. Sol-gels are polymeric materials that ...

The implications of organically-modified silica-based materials in electrochemical science is reviewed along with some selected recent trends in the field of functionalized and sol–gel silica electrochemistry. These recent trends include the electro-assisted generation of organosilica films on solid electrode surfaces, the preparation and applications of sol–gel derived composite (carbon, gold,...

We report on the fabrication and characterization of thick UV-patternable hybrid sol-gel films by spin coating using a modified sol-gel process. Thick coating of 25 microns with crack-free surface can be produced by one spin coating step. Thick layers of more than 100 μm can be obtained with a multi-coating process. Characterization using different techniques including optical microscope and at...

We report here the selective determination of dopamine (DA) using quantum-sized gold nanoparticles coated with charge selective ligands. Glutathione protected gold nanoparticles (GS-Au(25)) were synthesized and immobilized into a sol-gel matrix via thiol linkers. The GS-Au(25) modified sol-gel electrode was found to show excellent electrocatalytic activity towards the oxidation of DA but no act...

In chemical analysis and electrochemical catalysis modified electrodes have been used in a wide range. In addition to the several methods of electrode modification reported in literature, the sol-gel route offers a possibility of preparing ceramic like films under rather mild conditions. This enhances the possibility of incorporation of temperature sensitive particles such as enzymes, microorga...

Ta2O5 nanoparticles have been synthesized from alkoxy carboxylates of tantalum via the sol-gel route. Tantalum alkoxides were reacted with chlorocarboxylic acids in order to lower the susceptibility hydrolysis. When these modified alkoxy carboxylates were used in the sol-gel synthesis, they yielded Ta2O5 nanoparticles of better properties than those of the alkoxide-derived Ta2O5 nanoparticles. ...